Search results for "chemistry [Arsenates]"
showing 10 items of 2372 documents
Seasonal variability in silicate weathering signatures recorded by Li isotopes in cave drip-waters
2021
Abstract Silicate weathering is a critical process in Earth’s carbon cycle, but the fundamental controls on weathering are poorly understood and its response to future climate change is uncertain. In particular, the potential for changes in seasonality or extreme weather events to control silicate weathering rates or mechanisms has been little studied. Here, we use lithium (Li) isotope measurements in bimonthly sampled drip-waters from two caves in the Yorkshire Dales (U.K.) to assess the response of silicate weathering processes to changes in temperature and hydrology over seasonal timescales. While the caves are contained in limestone bedrock, the drip-water Li isotope signal predominantl…
Quantifying the impact of mechanical layering and underthrusting on the dynamics of the modern India-Asia collisional system with 3-D numerical models
2014
The impact of mechanical layering and the strength of the Indian lower crust on the dynamics of the modern India-Asia collisional system are studied using 3-D thermomechanical modeling. The model includes an Indian oceanic domain, Indian continental domain, and an Asian continental domain. Each domain consists of four layers: upper/lower crust, and upper/lower lithospheric mantle. The Tarim and Sichuan Basins are modeled as effectively rigid blocks and the Quetta-Chaman and Sagaing strike-slip faults as vertical weak zones. The geometry, densities, and viscosities are constrained by geophysical data sets (CRUST2.0, gravity, and seismology). Both static (no horizontal movement of model bound…
Two orogenic events separated by 2.6Ga mafic dykes in the Central Zone, Limpopo Belt, southern Africa
2017
Abstract The Limpopo Belt of southern Africa is a typical early Precambrian orogen that experienced two high-grade metamorphic events which are a key for understanding its tectonic evolution. There has been a long-standing debate on whether the Neoarchean (c. 2.65 Ga) or the Palaeoproterozoic (c. 2.0 Ga) tectono-thermal event records continental collision. The clear field relationship between deformed mafic dykes and the surrounding rocks is a powerful tool to help reconstructing the deformation history. Mafic dykes intruded the 3.3–3.1 Ga Sand River Gneiss Suite in the Central Zone of the Limpopo Belt near Musina, South Africa, and were classified in the past into older Causeway dykes and …
The Adamawa-Yadé domain, a piece of Archaean crust in the Neoproterozoic Central African Orogenic belt (Bafia area, Cameroon)
2017
Abstract New field observations, ages and geochemical data are presented for the Adamawa-Yade domain, forming part of Central African Orogenic Belt in Cameroon. This belt delineates the northern margin of the Congo craton and is part of the Braziliano/Pan-African orogenic system, which was formed during amalgamation of the West Gondwana continent at the end of the Neoproterozoic. U–Pb dating indicates that the protoliths of some orthogneisses from the Adamawa-Yade domain were emplaced during three distinct periods. Tonalite-Trondhjemite-Granodiorite (TTG) suites in the Makenene area intruded at ca. 3.0–2.5 Ga, and were affected by partial melting at ca. 2.08–2.07 Ga, during the Eburnean oro…
Improved constraints on open-system processes in fossil reef corals by combined Th/U, Pa/U and Ra/Th dating: A case study from Aqaba, Jordan
2019
Abstract Here we present 230Th/U, 231Pa/U as well as 226Ra/230Th isotope ratios from five fossil reef corals of Last Interglacial origin from the Gulf of Aqaba, Northern Red Sea. The results show clear evidence for open-system behaviour with strongly elevated δ234U values and U concentrations indicating post-depositional U addition. The combined application of all isotope systems enables us to better constrain the nature and timing of the open-system processes than only based on the 230Th/U data. Quantitative modelling of the diagenetic processes allowed us to reproduce the trends in the isotope ratios. Two of the five corals were probably affected by two separate phases of U addition with …
Results of the DEKORP 1 (BELCORP-DEKORP) deep seismic reflection studies in the western part of the Rhenish Massif
1991
Summary Within the DEKORP project (DEKORP: Deutsches Kontinentales Reflexionsseismisches Programm) a joint deep seismic reflection venture with the BELCORP (Belgian Continental Reflection Seismic Programme) group of the Belgian Geological Survey was carried out in 1987 across the Rhenish Massif, a part of the mid-European Variscides. This orogenic belt developed in the Upper Devonian/Carboniferous. Mostly Devonian rocks crop out at the surface. The Rhenish Massif is bordered by two sedimentary troughs: the sub-Variscan Foredeep in the north and the Permo-Carboniferous Saar-Nahe Basin in the south. In the east-west direction it is subdivided by the axial depression of the Eifel Nord-Sud Zone…
Turmoil at Turrialba Volcano (Costa Rica): Degassing and eruptive processes inferred from high-frequency gas monitoring
2016
Eruptive activity at Turrialba Volcano (Costa Rica) has escalated significantly since 2014, causing airport and school closures in the capital city of San Jose. Whether or not new magma is involved in the current unrest seems probable but remains a matter of debate as ash deposits are dominated by hydrothermal material. Here we use high-frequency gas monitoring to track the behavior of the volcano between 2014 and 2015 and to decipher magmatic versus hydrothermal contributions to the eruptions. Pulses of deeply derived CO2-rich gas (CO2/S-total>4.5) precede explosive activity, providing a clear precursor to eruptive periods that occurs up to 2weeks before eruptions, which are accompanied by…
H2O-content and temperature limit the explosive potential of rhyolite magma during Plinian eruptions
2019
Abstract Recent rhyolite eruptions on Earth have demonstrated their capacity to produce a multitude of hazards, including ash formation lasting months and impacting the large reaches of the southern hemisphere. Nevertheless, the underlying mechanisms driving these eruptions are not yet fully understood. Magmatic volatiles, especially H2O, dictate whether volcanic eruptions proceed explosively or effusively. Experimental evidence for the role played by H2O in driving explosive fragmentation is rare, in particular in the eruption of rhyolitic magma. Here we show that when hydrous rhyolitic obsidians from Chaiten Volcano (Chile) are experimentally heated above their glass transition temperatur…
Mapping fumarolic fields in volcanic areas: A methodological approach based on the case study of La Fossa cone, Vulcano island (Italy)
2016
Abstract Changes in the activity state of a volcano can be inferred by monitoring the steam flux from fumarolic fields, in terms of 4D (x, y, z, time) variations in temperature and extension of the zone. During the last decades, several studies in this field have been conducted worldwide, and at Vulcano island (Italy) in particular. Both direct and remotely sensed measurements have been used for identifying thermally anomalous areas, but the possible role of the hydrothermal alteration of volcanic products, producing a sealing effect that obscures the surface thermal evidence of fumarolic activity, have never been explored. The novelty of the present study, carried out at La Fossa cone (Vul…
First observations of the fumarolic gas output from a restless caldera: Implications for the current period of unrest (2005-2013) at Campi Flegrei
2013
[1] The fumarolic gas output has not been quantified for any of the currently deforming calderas worldwide, due to the lack of suitable gas flux sensing techniques. In view of resumption of ground uplift (since 2005) and the associated variations in gas chemistry, Campi Flegrei, in southern Italy, is one of the restless calderas where gas flux observations are especially necessary. Here we report the first ever obtained estimate of the Campi Flegrei fumarolic gas output, based on a set of MultiGAS surveys (performed in 2012 and 2013) with an ad-hoc-designed measurement setup. We estimate that the current Campi Flegrei fumarolic sulphur (S) flux is low, on the order of 1.5–2.2 tons/day, sugg…